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Hazardous Chemical Compounds & Hazardous Waste

When using organic solvents containing hazardous chemical compounds in a degreasing operation, a facility is required to track the amount of spent product accumulated each month and dispose of it as hazardous waste:

  • 1,1,1 Trichloroethane
  • Acetone
  • Benzene
  • Carbon Tetrachloride
  • Chlorinated Fluorocarbons
  • Isobutanol
  • Low flash point mineral spirits
  • Methanol
  • Methylene Chloride
  • Methyl Ethyl Ketone
  • Methyl Isobutyl Ketone
  • Ortho-Dichlorobenzene
  • Tetrachloroethylene
  • Toluene
  • Trichlorofluoromethane
  • Xylene

Hazardous waste requires special handling and proper disposal if it is:

  • A listed hazardous waste

As an example, a F001 hazardous waste are spent halogenated solvents used in degreasing: Tetrachloroethylene, Trichlorethylene, Methylene chloride, 1,1,1-Trichloroethane, Carbon Tetrachloride and chlorinated fluorocarbons; all spent solvent mixtures/blends used in degreasing containing, before use, a total of ten percent or more (by volume) of one or more of the above halogenated solvents or those solvents listed in F002, F004, and F005; and still bottoms from the recovery of these spent solvents and spent solvent mixtures.

Similar to a F001 hazardous waste, a F003 hazardous waste are spent non-halogenated solvents such as Xylene and Acetone.

Additionally, a F005 hazardous waste are spent non-halogenated solvents such as Toluene and Methyl Ethyl Ketone. As an example, spent lacquer thinner includes the ingredient Toluene at or above ten percent by volume prior to usage.

  • A characteristic hazardous waste (i.e., ignitable, toxic, reactive, or corrosive)
    • Ignitable (U.S. EPA Hazardous Waste No. D001) wastes can create fires under certain conditions, are spontaneously combustible, or have a flash point less than 60 °C (140 °F).
    • Corrosive (U.S. EPA Hazardous Waste No. D002) wastes are aqueous-based acids or bases (pH less than or equal to 2, or greater than or equal to 12.5)
    • Reactive (U.S. EPA Hazardous Waste No. D003) wastes are normally unstable and readily undergo violent change without detonating. They react violently or form potentially explosive mixtures with water.
    • Toxic (U.S. EPA Hazardous Waste Nos. D004–D043) wastes are harmful or fatal when ingested or absorbed. Examples include eight metals (D004–D011); cancelled pesticides (D012–D017); and toxic organics (D018– D043), including 12 with solvent applications.

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